Back-to-back milk drinks show the biggest gap. With a dual boiler, the steam side stays ready while the brew side works, so you are not waiting to switch modes between shots and milk.
Each boiler holds its own temperature, so brewing is less affected when you steam. That separation is the main reason buyers pay for a dual boiler.
If you make one espresso or one latte at a time, the switch from brewing to steaming is short enough that many buyers never notice it.